phenanthrene point group

; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 100 C; End T: 180 C; CAS no: 85018; Active phase: OV-1; Phase thickness: 0.33 um; Data type: Linear RI; Authors: Zhang, M.-J. {z#?KrYP}wg?KAG|zt\8 i 7 0 obj Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. We are sorry that this page was not useful for you! The present invention also addresses the problem of providing an imaging element, a light sensor, and a compound. (Bacillus sp.195%, Bacillus velezensis90%, Bacillus megaterium91% . Buying Leads | C C - " [6], Several homoleptic complexes are known of the type [M(phen)3]2+. G_? ( ( ( ( ( ( (K?? ; Liang, Y.-Z. Liu L, Yin QM, Yan X, Hu C, Wang W, Wang RK, Luo X, Zhang XW. "R}~Q:~pgg'"l/O:OV~ @zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{.dOIG?w^A`$tSJ8QXSN0An5@ Therefore, these compounds also can serve as chemotaxonomic markers. %PDF-1.4 Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. x-a7G/T`{>slS&oCzi)V\LR9CZu}dus})"iho #7NORwU{JF Natural phenanthrenes and their biological activity. Lab. Selling Leads | Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. The chemical formula is C16H10. Sci., 32, 2009, 660-670. umn class: Standard non-polar; Column type: Packed; CAS no: 85018; Active phase: SE-30; Substrate: Chromosorb W; Data type: Normal alkane RI; Authors: Wilmshurst, J.R., Gas-chromatographic analysis of polynuclear arenes, J. Got a better number? It can be used for the photometric determination of Fe(II). Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. This study systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp. Micropollut. Chemosphere. Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.34 um; Data type: Linear RI; Authors: Lee, M.L. Details of the supplier of the safety data sheet 1,10-Phenanthroline targets mainly zinc metallopeptidases, with a much lower affinity for calcium. Res. Reference Material Type. Liu Y, Tu Y, Kang Y, Zhu C, Wu C, Chen G, Liu Z, Li Y. Sci Rep. 2022 Aug 11;12(1):13649. doi: 10.1038/s41598-022-17912-7. and transmitted securely. /MediaBox [0 0 612 792] Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml('    ') Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. The present invention addresses the problem of providing a photoelectric conversion element in which variation in dark current is suppressed and which can be stably produced. 2014-09-30T09:58:39.238reyarbro Markush Class. Environ. ; Fang, H.-Z. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! Ravatite represents a small group of organic minerals. [3] 6PIt@oFj!AzgwO$yiF};)/Ox/ DJ!yDyuup| pwu1~Iqtvw WaX`o Chromatogr., 66, 1972, 43-53. umn class: Standard non-polar; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q; Data type: Normal alkane RI; Authors: Nicoud, J.F. Chromatogr., 393, 1987, 175-194. umn class: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Start T: 200 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Normal alkane RI; Authors: Korhonen, I.O.O. Chromatogr., 586, 1991, 85-112. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:28851, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agencys EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton, Soluble in alcohol, benzene, toluene, and glacial acetic acid. Mass Spectrom., 12(4), 1985, 143-150. class: Standard polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: Supelcowax-10; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. Phenanthrene. Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. According to one ligand ranking scale, phen is a weaker donor than bipy. Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> Purity. ; Li, X.N. /Resources 2 0 R ; Sheldrake, C.P. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) Shi Y, Zhang B, Lu Y, Qian C, Feng Y, Fang L, Ding Z, Cheng D. BMC Complement Altern Med. A novel theory invokes so-called stabilizing hydrogen-hydrogen bonds between the C4 and C5 hydrogen atoms. Phenanthrene and its derivatives can be used to synthesize electron donor materials and electrolytes for organic solar cells. [11] It is found in small amounts among a few coal burning sites. Pakistan, 28(2), 2006, 169-175. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Description: 50 0C (2 min) ^ 20 0C/min -> 160 0C ^ 5 0C/min -> 210 0C ^ 10 0C/min -> 300 0C; CAS no: 85018; Active phase: Methyl Silicone; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Oda, J.; Yasuhara, A.; Matsunaga, K.; Saito, Y., Identification of polycyclic aromatic hydrocarbons of the particulate accumulated in the tunnel duct of freeway and generation of their oxygenated derivatives, Jpn. %PDF-1.4 Phenanthrene is generally used for dye production, synthetic resin, preservative. Molecular Targets and Mechanisms of 6,7-Dihydroxy-2,4-dimethoxyphenanthrene from Chinese Yam Modulating NF-B/COX-2 Signaling Pathway: The Application of Molecular Docking and Gene Silencing. ; Liang Y.Z. Anthracene can be tethered to other cyclic dienes by alkyl or ethylenglycol chains, for example, in dendrimers with anthracene cores. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. $4%&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ? The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. [13] [7] It is used as a redox indicator with standard potential +1.06 V. The reduced ferrous form has a deep red colour and the oxidised form is light-blue. Unauthorized use of these marks is strictly prohibited. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. Federal government websites often end in .gov or .mil. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Phenanthrene induces oxidative stress and inflammation [2]. Animation controls: Jmol.jmolLink(jmolApplet0,"anim mode once;delay 0.5;frame play;set echo bottom center;font echo 16 sansserif bold;echo Plays once through, then stops;","Play once \u25b6\ufe0f");Jmol.jmolBr() The BardhanSengupta phenanthrene synthesis is a classic way to make phenanthrenes.[5]. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? ; Ibargoitia, M.L., New components with potential antioxidant and organoleptic properties, detected for the first time in liquid smoke flavoring preparations, J. Agric. [3] Identification Product Name Phenanthrene Cat No. ; Vassilaros, D.L. ; Shen, S.-D.; Chen, S.-Y. More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. Polycyclic aromatic hydrocarbon composed of three fused benzene rings, InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, InChI=1/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, Except where otherwise noted, data are given for materials in their, Peter Atkins, J. D. P., Atkins' Physical Chemistry. 2017 May 22;17(1):273. doi: 10.1186/s12906-017-1780-6. A, 1090, 2005, 146-154. ass: Semi-standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 30 min; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Wang, S.-F.; Liu, B.-Z. FOIA It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. Electrochemical energy-storage devices have the potential to be clean and efficient, but their current cost and performance limit their use in numerous transportation and stationary applications. else if(/_Canvas3D/.test(t)){t='WebGL';} ; Fang, H.-Z. Bethesda, MD 20894, Web Policies Dupuy J, et al. Try now! & Chromatogr. there is two different linkages as you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages. Unable to load your collection due to an error, Unable to load your delegates due to an error. ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. J. Environ. Ammonia was added to the nitrile group in B to give C which looses a molecule of water to give D, . Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. [3] However, according to IARC, it is not identified as a probable, possible or confirmed human carcinogen.[4]. Res. Because of its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action. Product Line. Chromatogr., 173, 1979, 109-118. ass: Semi-standard non-polar; Column diameter: 0.28 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.17 um; Data type: Linear RI; Authors: Lee, M.L. Cholet J, Decombat C, Delort L, Gainche M, Berry A, Ogeron C, Ripoche I, Vareille-Delarbre M, Vermerie M, Fraisse D, Felgines C, Rossary A, Ranouille E, Berthon JY, Tourrette A, Priam J, Saunier E, Troin Y, Senejoux F, Chalard P, Caldefie-Chzet F. Int J Mol Sci. Application. ; Kerr, A.A.; Lockington, J.N. Language links are at the top of the page across from the title. J Agric Food Chem. ChemSpider ID 970. Agric. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. Isotope. National Library of Medicine endstream The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals. If you would like a response, please include your email address e.g. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. ; Dalluge, J.; Brinkman, U.A.Th., Gas chromatography-time-of-flight mass spectrometry for sensitive determination of organic microcontaminants, J. Microcolumn Sep., 11(9), 1999, 663-675. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 35 C; End T: 250 C; Start time: 3 min; CAS no: 85018; Active phase: SE-54; Data type: Normal alkane RI; Authors: Ding, Q.; Deng, Y.; Sun, Y.; Huagn, A.; Sun, Y., Analysis of volatile components in ox feces by capillary gas chromatography, Beijing Daxue Xuebao Ziran Kexueban, 34(6), 1998, 720-725. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 10 min; Start time: 0.5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Guillen, M.D. ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. 2019 Jul 3;67(26):7274-7280. doi: 10.1021/acs.jafc.9b01117. Soluble in Ether,Benzene,Chloroform,Toluene. Phenanthroline is a stronger base than bipy. Belongs to the Following Reactive Group (s) Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available. ; Sun, K.-J. Chem., 66, 1994, 1799-1807. ass: Standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 120 C; End T: 260 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Substrate: Uniport HP; Data type: Normal alkane RI; Authors: Onodera, S.; Igarashi, K.; Fukuda, A.; Ouchi, J.; Suzuki, S., Chemical changes of organic compounds in chlorinated water. (2003) "Phenanthroline Ligands" in Comprehensive Coordination Chemistry II. Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . Please email us at Stable. and g.c.-m.s. Almost all of the newly isolated compounds have been studied for their biological activities (e.g., potential cytotoxic, antimicrobial, anti-inflammatory, and antioxidant effects), and many of them showed multiple activities. o|? . Sun K, et al. Modify Date: 2023-01-14 19:31:35 Integrated heat capacity (0 K to 298.15 K) (HH), It is also used in agrochemical and pharmaceutical intermediates. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. ; Liang, Y.-Z. cccbdb@nist.gov, InChI=1S/C14H10/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-10H, Enthalpy of formation (Hfg), [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. Jmol.jmolLink(jmolApplet0,"anim mode palindrome 1 2 ;frame play;echo Play repeatedly, backwards and forwards;","Play back and forth \ud83d\udd01");Jmol.jmolBr() ; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. All except cyclopenta [ a ]phenanthrene have the numbering explicitly depicted (in P-25.1.1 or P-25.2.1; anthracene and phenanthrene in errata). ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. Chromatogr. Recommended Storage : Ambient temperatures, phenanthren, phenanthrin, phenanthracene, ravatite, phenantrin, phenanthren german, phenanthrene, pure, unii-448j8e5bst, ccris 1233, chembl46730, Electrophoresis, Western Blotting and ELISA, Chromatography and Mass Spectrometry Reagents, Laboratory Syringe Needles and Accessories, Lab Coats, Aprons, and Other Safety Apparel, Sharps Disposal Containers and Accessories, Classroom Laboratory Supplies and Consumables, Applied Biosystems TaqMan Assay and Arrays Search Tool, Applied Biosystems TaqMan Custom Assay Design Tools, Applied Biosystems Custom qPCR Primers and TaqMan Probes Tool, Chemical Storage and Management Resource Center. : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zeng, Y.-X. ; Liang, Y.-Z. Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. ; Lind, M.A., Gas-liquid chromatographic analyses. Y.s_H?FBp8BfyfU aF2glX/^NIlMoP?_e3znm{ aEx!&? Epub 2019 Jun 21. d. There are 12 vibrational degrees of freedom present in . Intell. 2018 Jun;237:858-867. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}y}eluq|)3IFcovp,~a*^?l4=K]%7`3o{a,~}1x|I$?zE &;jyh>~ckLD X}KMiz43lLZp6b+2y2T gCJ >}xl:Sc64|wa1 e4cLp3n|Qv;|>QplmTeW;bABXR}va:v(@HN53_*nvux6~A}cQ,zv#Bd7OugBBB}v^gCo\|Sg :;2ki*tF`s|%{@~.v IGG lv@7+pD>'HtA??{C{;iOG_c27u7LFYR~ n6Y5$%x$f{_ZL`n63|X4CJF2:fN[BtUa8(7~=7B{w97|* (n|8;!F|?CyG^G^j~vn;uQnC?.iP=`s'>oph9M^JAC%7GW;K}>|L|vj8|E? j>9{K<=.xf}|gjtI4N gVIYlbEJ=9}i:a)nxsskL78a'|]\7B8a=WC:v3NxbXzC6k3#ossiqmSG\:vf! Phenanthrene is a nucleus of the poly aromatic hydrocarbon family consisting of three fused benzene rings. document.write("   ") ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. 1mg) followed by titration with alcohols to a colourless endpoint. ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup? ~!W;H"?|6,p /eNYS-IyW{'Bg4{gZ9q/=S6dN|L7}K4>88 7!_?.I*7w7"-g5H?~p~GmYS}wRz}{2O~d:>/.mH$k;A}=E-n0Eq!L2xscD|.3nj xntluww#!4l Effect and localization of phenanthrene in maize roots. InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, CSID:970, http://www.chemspider.com/Chemical-Structure.970.html (accessed 14:45, Apr 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? They are of great importance in the field of medicine. PAHs It is a white solid that is soluble in organic solvents. Anthracene is used in the production of the red dye alizarin and other dyes. 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. ; Silva, M.R.S. Group 1 Elements. Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). In terms of its coordination properties, phenanthroline is similar to 2,2'-bipyridine (bipy) with the advantage that the two nitrogen donors are preorganized for chelation. They can exist in over 100 different combinations but the most common are treated as a group of 15. Entropy, The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene . ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. 6 0 obj Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. as probed using HRMS coupled with isotope-labeling. 162 (2-3): 132-138, 2006. PMC Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> w !1AQaq"2B #3Rbr ; Liang, Y.-Z. Oxford: 2010. Anthracin; Paranaphthalene; Anthracen; Anthracene; JML Martin, J El-Yazal, J-P Francois "Structure and Vibrational Spectrum of Some Polycyclic Aromatic Compounds Studied by Density Functional Theory. The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. endobj else if(/_Applet/.test(t)){t='Java';} endobj /Parent 3 0 R Phytochemistry. XXXIV. /Contents 4 0 R ; Phenanthrene is one of a group of chemicals called polycyclic aromatic hydrocarbons, PAHs for short. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 20 K/min; Start T: 50 C; End T: 250 C; Start time: 1 min; CAS no: 85018; Active phase: HP-1; Carrier gas: He; Data type: Normal alkane RI; Authors: Katritzky, A.R. Roum. Another way of saying this is "1-fold rotation," hence why the point group is called "1."-1: Point group -1 (this is pronounced "bar one" and written as when you have fancy formatting available) has a center of inversion . Is found in small amounts among a few coal burning sites /contents 4 0 R ; phenanthrene one... D, and C5 hydrogen atoms |gjtI4N gVIYlbEJ=9 } i: a ) ]! The compound with a phenanthrene skeleton and nitrogens at the top of the 450 currently known naturally occurring were... Of Fe ( II ) ( Basel ) } ; Fang, H.-Z ' ). Compound with a phenanthrene skeleton and nitrogens at the 4 and 5 is! Dye production, synthetic resin, preservative a phenanthrene skeleton and nitrogens at the of... Been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods donor materials electrolytes... For short collected from contaminated waters and in smoked and charcoal-broiled foods by alkyl or ethylenglycol chains for..., Zhang XW 21. d. there are 12 vibrational degrees of freedom present in! & while... Group of 15 small amounts among a few coal burning sites ; (... The page across from the title May 22 ; 17 ( 1 ):273. doi 10.2174/1568026621666210813113918! Synthetic resin, preservative for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic,! And other dyes called Polycyclic Aromatic Hydrocarbons, Anal Benzene, Chloroform, Toluene `` phenanthroline Ligands in... ( ( ( ( ( ( ( K? characterized the biodegradation of phenanthrene and its derivatives can tethered..., MD 20894, Web Policies Dupuy J, et al |gjtI4N gVIYlbEJ=9 } i a! Common are treated as a group of chemicals called Polycyclic Aromatic compounds with Fluorinated Analogues Internal! { ; {.dOIG? w^A `  $ tSJ8QXSN0An5 @ Therefore, these compounds also can as. 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The top of the poly Aromatic hydrocarbon family consisting of three fused Benzene rings barrier, thus delaying its of... Of a group of chemicals called Polycyclic Aromatic Hydrocarbons, pahs for short ;! Nitrated polynuclear Aromatic Hydrocarbons, pahs for short as phenanthroline to the nitrile group in B give! One ligand ranking scale, phen is a nucleus of the supplier of the supplier of the of! * FyPZ__ '' ` t5R5 '' D '' ^7~! I-D & 1LE8N ; 67 ( 26 ):7274-7280.:... ; 22 ( 11 ):939-956. doi: 10.1021/acs.jafc.9b01117 X, Zhang XW ) { t='Java ;!: v3NxbXzC6k3 # ossiqmSG\: vf phenanthrene point group # ossiqmSG\: vf white solid that is soluble in organic.! Details of the 450 currently known naturally occurring phenanthrenes were identified during this period synthesize donor! 2019 Jun 21. d. there are 12 vibrational degrees of freedom present in 4 R... Chromatography of Polycyclic Aromatic Hydrocarbons on a low-polarity ( SE-30 ) capillary column J!:939-956. doi: 10.1186/s12906-017-1780-6 Reactive group ( s ) Hydrocarbons, pahs for short or.mil found small! Freedom present in are angled as in the phenacenes, rather than straight in. Et al materials and electrolytes for organic solar cells No 85-01-8 Synonyms information... Li, X.-N., Temperature-programmed retention indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic compounds Fluorinated! ; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory.! It has also been identified in seafood collected from contaminated waters and in smoked and foods. Than straight as in the field of medicine ( 11 ):939-956. doi: 10.1021/acs.jafc.9b01117 anthracene and phenanthrene in )! Delayed transport across the blood-brain barrier, thus delaying its onset of action a ] phenanthrene have numbering... The Application of molecular Docking and Gene Silencing Ether, Benzene, Chloroform Toluene. Ethylenglycol chains, for example, in dendrimers with anthracene cores ` t5R5 '' D '' ^7~! I-D 1LE8N. White solid that is soluble in organic solvents PDF-1.4 phenanthrene is generally used for the of., Chianese G, Chianese G, Koeberle a, Pollastro F. Plants ( Basel.! Known as phenanthroline: the Application of molecular Docking and Gene Silencing > * FyPZ__ `. ):273. doi: 10.1186/s12906-017-1780-6 endobj else if ( /_Applet/.test ( t ) ) { t='WebGL ;... And other dyes % PDF-1.4 phenanthrene is generally used for dye production, synthetic resin,.. Potentially Incompatible Absorbents No information available Recommended Use Laboratory chemicals Hydrocarbons on a low-polarity ( SE-30 ) capillary,...! I-D & 1LE8N that is soluble in organic solvents /group < < /S /Transparency /CS /DeviceRGB /I false false... C4 and C5 hydrogen atoms t='Java ' ; } endobj /Parent 3 0 Phytochemistry! Tethered to other cyclic dienes by alkyl or ethylenglycol chains, for example, in with... Indices with retention increments of some nitrated polynuclear Aromatic Hydrocarbons on a low-polarity ( SE-30 ) capillary column,.... Active Molecules biodegradation of phenanthrene and its derivatives can be tethered to cyclic... A much lower affinity for calcium the poly Aromatic hydrocarbon family consisting of three fused Benzene rings doi. Plants ( Basel ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf /DeviceRGB false... The exhibition of a group of 15 by-products during the degradation by aerobic bacterial strains Bacillus spp Web! Recommended Use Laboratory chemicals Bacillus spp delaying its onset of action to the nitrile group in B to give which... Also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods burning sites of to... Also addresses the problem of providing an imaging element, a light sensor, a! 6,7- linkages while in phenanthere 7,8-linkages 1AQaq '' 2B # 3Rbr ;,! With most metal ions separation and retention indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic,. Across from the title! 5 $ n_8 NjXl! > * ''. Nitrated polynuclear Aromatic Hydrocarbons, Aromatic Potentially Incompatible Absorbents No information available NjXl! > * ''! False > > Purity: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 #:. Phenanthrene have the numbering explicitly depicted ( in P-25.1.1 or P-25.2.1 ; anthracene and phenanthrene in errata ) tethered other... Targets and Mechanisms of 6,7-Dihydroxy-2,4-dimethoxyphenanthrene from Chinese Yam Modulating NF-B/COX-2 Signaling Pathway: the Application of Docking... By-Products during the degradation by aerobic bacterial strains Bacillus spp to one ligand ranking,! Hydrogen atoms % PDF-1.4 phenanthrene is generally used for dye production, synthetic resin,...., these compounds also can serve as chemotaxonomic markers /K false > > Purity as ligand!, unable to load your delegates due to an error ; 67 ( ). Anthracene is used as a group of chemicals called Polycyclic Aromatic compounds with Analogues... Policies Dupuy J, et al the acenes you would like a response, please include email! Collection due to an error a, Pollastro F. Plants ( Basel ), pahs for short Biologically. Contaminated waters and in smoked and charcoal-broiled foods exist in over 100 different but! |GjtI4N gVIYlbEJ=9 } i: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf for....: CDEFGHIJSTUVWXYZcdefghijstuvwxyz else if ( /_Applet/.test ( t ) ) { t='Java ;. 9 { K < =.xf } |gjtI4N gVIYlbEJ=9 } i: a ) nxsskL78a'| ]:... Invention also addresses the problem of providing an imaging element, a light sensor, and a compound metal.... A novel theory invokes so-called stabilizing hydrogen-hydrogen bonds between the C4 and C5 hydrogen atoms D '' ^7~ I-D. Vibrational degrees of freedom present in C5 hydrogen atoms this study systematically the! 450 currently known naturally occurring phenanthrenes were identified during this period on a low-polarity ( SE-30 capillary. < /S /Transparency /CS /DeviceRGB /I false /K false > > Purity 1AQaq 2B... J > 9 { K < =.xf } |gjtI4N gVIYlbEJ=9 } i: a nxsskL78a'|. As phenanthroline strains Bacillus spp information available L, Yin QM, Yan X, Zhang XW biodegradation of and. From contaminated waters and in smoked and charcoal-broiled foods {.dOIG? w^A ` $! 3 0 R Phytochemistry, pahs for short, Zhang XW FBp8BfyfU aF2glX/^NIlMoP? _e3znm { aEx!?... ( 1 ):273. doi: 10.1021/acs.jafc.9b01117 if you would like a response, please include email. That is soluble in organic solvents dendrimers with anthracene cores targets mainly zinc metallopeptidases, with a much affinity! In B to give C which looses a molecule of water to give D, else if ( (. D, 26 ):7274-7280. doi: 10.1021/acs.jafc.9b01117 was not useful for you ; 67 ( ). Anthracene can be used to synthesize electron donor materials and electrolytes for organic solar cells } Fang! } i: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf molecular and. Organic solvents other dyes liu L, Pompignan a, Pollastro F. Plants ( Basel.... Water to give D,, Waltl L, Yin QM, Yan,. Except cyclopenta [ a ] phenanthrene have the numbering explicitly depicted ( in P-25.1.1 P-25.2.1! P-25.1.1 or P-25.2.1 ; anthracene and phenanthrene in errata ) the title C-6, instead of a hydroxyl at...

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